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Elastic, Inelastic, and Photofragment Scattering from Crossed Molecular Beams

Citation

Reid, Brian Paul (1986) Elastic, Inelastic, and Photofragment Scattering from Crossed Molecular Beams. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/xz77-2x37. https://resolver.caltech.edu/CaltechTHESIS:10232019-145508172

Abstract

Three sets of crossed molecular beam scattering experiments are described. In the first experiment, total differential cross sections are measured for collisions between two methane molecules. Treating the scattering as elastic, these cross sections are used to determine an isotropic intermolecular potential energy function for the methane-methane system. The second experiment involves the measurement of total differential cross sections and time-of-flight spectra for neon-chlorine scattering. These data are modeled using the infinite order sudden approximation for rotationally inelastic scattering, and an anisotropic potential function for neon-chlorine is determined. In the third experiment, the angular and time-of-flight distributions for the products of the three-body photofragmentation of 1,2-diiodotetrafluoroethane at 266 nm are measured. These data are analyzed to determine the product translational energy distributions.

Item Type:Thesis (Dissertation (Ph.D.))
Subject Keywords:Chemistry
Degree Grantor:California Institute of Technology
Division:Chemistry and Chemical Engineering
Major Option:Chemistry
Thesis Availability:Public (worldwide access)
Research Advisor(s):
  • Sparks, Randal K.
Thesis Committee:
  • Beauchamp, Jesse L. (chair)
  • Sparks, Randal K.
  • Bercaw, John E.
  • Kuppermann, Aron
  • Weitekamp, Daniel P.
Defense Date:4 April 1986
Record Number:CaltechTHESIS:10232019-145508172
Persistent URL:https://resolver.caltech.edu/CaltechTHESIS:10232019-145508172
DOI:10.7907/xz77-2x37
Related URLs:
URLURL TypeDescription
https://doi.org/10.1063/1.449689DOIArticle adapted for Chapter 2.
Default Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:11851
Collection:CaltechTHESIS
Deposited By: Melissa Ray
Deposited On:23 Oct 2019 22:11
Last Modified:16 Apr 2021 23:07

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