Citation
Shah, Usha (1964) α-Carbonium Ion Stabilization in Derivatives of Cyclopentadienylmanganese Tricarbonyl. Master's thesis, California Institute of Technology. doi:10.7907/GQ3E-6784. https://resolver.caltech.edu/CaltechTHESIS:05032010-131343121
Abstract
A study has been made of the solvolyses of some acetoxy and trifluoroacetoxy compounds of cyclopentadienylmanganese tricarbonyl and of benzene. Also, a study of some addition reactions to the double bond of vinyl cyclopentadienylmanganese tricarbonyl has been made. Both studies show that an α-cyclopentadienylmanganese tricarbonyl carbonium ion is less stable than an α-ferrocenylcarbonium ion, but more stable than an α-phenylcarbonium ion.
| Item Type: | Thesis (Master's thesis) |
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| Subject Keywords: | (Chemistry) |
| Degree Grantor: | California Institute of Technology |
| Division: | Chemistry and Chemical Engineering |
| Major Option: | Chemistry |
| Thesis Availability: | Public (worldwide access) |
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| Thesis Committee: |
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| Defense Date: | 1 January 1964 |
| Record Number: | CaltechTHESIS:05032010-131343121 |
| Persistent URL: | https://resolver.caltech.edu/CaltechTHESIS:05032010-131343121 |
| DOI: | 10.7907/GQ3E-6784 |
| Default Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. |
| ID Code: | 5766 |
| Collection: | CaltechTHESIS |
| Deposited By: | Tony Diaz |
| Deposited On: | 17 Jun 2010 15:43 |
| Last Modified: | 29 Jan 2024 22:04 |
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