Citation
Clarke, Mildred Allen (1971) Studies Leading to Iodine-Tagged Crosslinked Polybutadiene. Master's thesis, California Institute of Technology. doi:10.7907/7951-NC71. https://resolver.caltech.edu/CaltechTHESIS:04222010-090826127
Abstract
Work leading to the synthesis of uniformly crosslinked poly-butadiene with iodine tags at both ends of a small percentage of the crosslinking chains is described. The following reactions have been investigated: conversion of dibromopolybutadiene to diiodopolybutadiene; conversion of dihydroxypolybutadiene to polybutadiene diisocyanate; chain extension of polybutadiene diisocyanate with 3-dirnethylamino-1, 2-propane-diol to form a linear polybutadiene with pendant dimethylamino groups (PBPA); crosslinking of the PBPA by quaternization of the amine groups with diiodopolybutadiene; and formation of the amine salt of PBPA by treatment with hydrochloric acid. Mechanical properties of PBPA, its HC1 salt, and the cross-linked polybutadiene were determined by free torsional oscillation. Salt formation apparently leads to pseudo-crosslinking of the polymer by association of the ionic groups, so that the polymer exhibits elastomeric behavior between -30° and 40°C. Crosslinking of PBPA by quaternization of the amine groups with diiodopolybutadiene extends the elastic region to 130°C, where creep begins due to degradation of the polymer.
Item Type: | Thesis (Master's thesis) |
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Subject Keywords: | (Chemistry) |
Degree Grantor: | California Institute of Technology |
Division: | Chemistry and Chemical Engineering |
Major Option: | Chemistry |
Thesis Availability: | Public (worldwide access) |
Research Advisor(s): |
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Thesis Committee: |
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Defense Date: | September 1970 |
Record Number: | CaltechTHESIS:04222010-090826127 |
Persistent URL: | https://resolver.caltech.edu/CaltechTHESIS:04222010-090826127 |
DOI: | 10.7907/7951-NC71 |
Default Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. |
ID Code: | 5734 |
Collection: | CaltechTHESIS |
Deposited By: | Tony Diaz |
Deposited On: | 22 Jun 2010 20:40 |
Last Modified: | 20 Jun 2024 20:57 |
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