Deformation-induced amorphization of Cu-Ti intermetallics

Citation

Askenazy, Philip Douglas (1992) Deformation-induced amorphization of Cu-Ti intermetallics. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/qssf-8m12. https://resolver.caltech.edu/CaltechETD:etd-07192007-131937

Abstract

Two methods of inducing amorphization in Cu-Ti intermetallic compounds by mechanical means have been investigated. Ingots of compositions Cu35Ti65 and Cu33.3Ti66.7 were rapidly quenched into ribbons. The microstrucure consisted largely of microcrystals in an amorphous matrix, which were either quenched in or grown by annealing. The ribbons were cold-rolled, which reduced their effective thickness by a factor of about 8. The status of the intermetallic compound CuTi2 was monitored by x-ray diffraction and transmission electron microscopy (TEM). The crystals were found to amorphize as rolling progressed. This behavior was not reproduced in polycrystalline samples that had no amorphous matrix present initially. The presence of the amorphous phase is thus necessary for amorphization of the crystal: it eliminates the need to nucleate the new glass, and it prevents the ribbon from disintegrating at high deformation stages. It may also change the deformation mechanism that occurs in the crystals, retarding the onset of amorphization. Diffuse scattering in close-packed directions is similar to that seen in electron irradiation experiments. It is postulated that the chemical disorder present in antiphase boundaries caused by deformation raises the free energy of the crystal higher than that of the amorphous phase.

Ingots of the same compound were worn against each other in a custom-built wear apparatus. The design eliminates iron contamination of the wear sample and requires relatively small quantities of material. Alteration of the surface structure was monitored by plane-view and cross-sectional TEM. Larger subsurface crystals exhibit diffuse scattering, similar to that found in the rolled samples. A wide range of grain sizes was observed, due to the inhomogeneous nature of the wear process. An unusual phase was observed at the surface, consisting of a nanometer-scale mixture of aligned nanocrystalline regions and disordered areas. Some amorphous phase is possibly present as well. It is postulated a combination of high unidirectional strain rates and small grain sizes forces the nanocrystals to accommodate deformation by disordering in one direction. Deformation in additional directions might presumably cause the structure to go completely amorphous.

Thesis Files