Citation
Greene, Blake Bennet (2004) Progress Toward the Total Synthesis of Salvadione-A and Related Diterpenoids. Master's thesis, California Institute of Technology. doi:10.7907/AAPZ-W246. https://resolver.caltech.edu/CaltechETD:etd-06252004-084128
Abstract
Herein, we report our progress toward the total synthesis of salvadione-A, a structurally complex triterpenoid isolated from Salvia bucharica. We document a model system of our tandem Claisen/Cope/Diels-Alder strategy. Additionally, we describe the evolution of our strategy toward the synthesis of three structurally related diterpenoids-coulterone, cyclocoulterone, and komaroviquinone--from a cyclopropanation/Friedel-Crafts route to an anionic homo-Fries/intramolecular Barbier cyclization pathway.
| Item Type: | Thesis (Master's thesis) |
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| Subject Keywords: | Chemistry |
| Degree Grantor: | California Institute of Technology |
| Division: | Chemistry and Chemical Engineering |
| Major Option: | Chemistry |
| Thesis Availability: | Public (worldwide access) |
| Research Advisor(s): |
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| Thesis Committee: |
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| Defense Date: | 1 March 2004 |
| Record Number: | CaltechETD:etd-06252004-084128 |
| Persistent URL: | https://resolver.caltech.edu/CaltechETD:etd-06252004-084128 |
| DOI: | 10.7907/AAPZ-W246 |
| Default Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. |
| ID Code: | 2720 |
| Collection: | CaltechTHESIS |
| Deposited By: | Imported from ETD-db |
| Deposited On: | 28 Jun 2004 |
| Last Modified: | 08 Nov 2023 00:39 |
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