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Small Molecule Reactivity of Trisphosphine-Supported Iron and Cobalt Complexes

Citation

Deegan, Meaghan Marie (2020) Small Molecule Reactivity of Trisphosphine-Supported Iron and Cobalt Complexes. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/QDAW-M003. https://resolver.caltech.edu/CaltechTHESIS:09252019-210323106

Abstract

The work described in this thesis emphasizes accessing novel reactivity patterns in the activation of carbon monoxide, dinitrogen, and dihydrogen by leveraging phosphine-supported iron and cobalt complexes. In Chapters 2 and 3, systems that access CO and N2 reductive functionalization from highly reduced Fe-hydride precursors are described. These systems access productive C-H and N-H bond forming steps from hydride precursors that ultimately allows for the liberation of four-electron reduced products through novel chemical pathways. Chapter 4 describes an unusual example of a terminal cobalt carbyne through the O-functionalization of a carbonyl complex. Next, in Chapter 5, we consider electronically unusual examples of dihydrogen complexes and explore their propensity for accessing H-atom and hydride transfer. Finally, to conclude, Chapter 6 details our synthetic efforts targeting the synthesis of a terminal Fe-carbide complex through the cleavage of a thiocarbonyl precursor.

Item Type:Thesis (Dissertation (Ph.D.))
Subject Keywords:Iron; cobalt; carbon monoxide; dihydrogen; dinitrogen
Degree Grantor:California Institute of Technology
Division:Chemistry and Chemical Engineering
Major Option:Chemistry
Thesis Availability:Public (worldwide access)
Research Advisor(s):
  • Peters, Jonas C.
Thesis Committee:
  • Agapie, Theodor (chair)
  • Fu, Gregory C.
  • Reisman, Sarah E.
  • Peters, Jonas C.
Defense Date:4 September 2019
Funders:
Funding AgencyGrant Number
NIHGM070757
Department of Energy (DOE)0235032
Record Number:CaltechTHESIS:09252019-210323106
Persistent URL:https://resolver.caltech.edu/CaltechTHESIS:09252019-210323106
DOI:10.7907/QDAW-M003
Related URLs:
URLURL TypeDescription
https://doi.org/10.1021/jacs.6b12444DOIPublished content for Chapter 2
https://doi.org/10.1039/C8SC02380HDOIPublished content for Chapter 3.
https://doi.org/10.1039/C9CC04032CDOIPublished content for Chapter 4.
ORCID:
AuthorORCID
Deegan, Meaghan Marie0000-0002-7633-2074
Default Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:11801
Collection:CaltechTHESIS
Deposited By: Meaghan Deegan
Deposited On:25 Oct 2019 00:30
Last Modified:27 May 2021 00:06

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