Citation
Tomooka, Craig Shigeru (1999) Use of Manganese(V) Nitrides as Enantioselective Nitrogen-Transfer Reagents. Master's thesis, California Institute of Technology. doi:10.7907/6t7v-s157. https://resolver.caltech.edu/CaltechTHESIS:12062017-140954903
Abstract
Once activated, manganese(V) nitrides have been shown to efficiently transfer nitrogen to furanoid. glycals. This process, followed by hydrolysis, forms the corresponding amino alcohols in high yield and diastereoselectivity. The isolation of an intermediate oxazoline and the ability to form this oxazoline from the amino alcohol was also discovered. The formation of chiral manganese nitrides is also described. After considerable experimentation, the transfer of nitrogen in these cases resulted in enantiomeric excesses of up to 92% accompanied by high yields.
| Item Type: | Thesis (Master's thesis) |
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| Subject Keywords: | Chemistry |
| Degree Grantor: | California Institute of Technology |
| Division: | Chemistry and Chemical Engineering |
| Major Option: | Chemistry |
| Thesis Availability: | Public (worldwide access) |
| Research Advisor(s): |
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| Thesis Committee: |
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| Defense Date: | 27 September 1998 |
| Record Number: | CaltechTHESIS:12062017-140954903 |
| Persistent URL: | https://resolver.caltech.edu/CaltechTHESIS:12062017-140954903 |
| DOI: | 10.7907/6t7v-s157 |
| Default Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. |
| ID Code: | 10592 |
| Collection: | CaltechTHESIS |
| Deposited By: | Benjamin Perez |
| Deposited On: | 06 Dec 2017 22:35 |
| Last Modified: | 30 Nov 2022 00:02 |
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