Citation
Ferington, Thomas Edwin (1952) Observations on the Interaction of Ion Exchange Resins with Some Cupric Compounds. Master's thesis, California Institute of Technology. doi:10.7907/CMRX-8587. https://resolver.caltech.edu/CaltechTHESIS:10162017-102130831
Abstract
The interaction of the Sulfonic Acid Resin, Nalcite HCR, with CuII halide solutions was studied in hope of obtaining dissociation constants for the complex ions CuX+. The fact that CuX+ is absorbed by the resin to an appreciable extent prevented the attainmnet of this goal. It was found in the case of CuF+ that the complex ion is absorbed even more strongly than Cu++. The presence of a Cu++-F- complex was indicated by spectrophotometric observations.
The action of the carboxylic acid resin, IRC - 50 was studied in a column. It was found that the volume of the resin in the Cu++ salt form depended on the salt with which the resin was treated. In the case of solutions of Cu(OAc)2 it was found that Cu(OAc)+ was taken into the resin as well as Cu++.
A titration curve for IRC - 50 with NaOH in solutions of ionic strength one is given.
| Item Type: | Thesis (Master's thesis) |
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| Subject Keywords: | Chemistry |
| Degree Grantor: | California Institute of Technology |
| Division: | Chemistry and Chemical Engineering |
| Major Option: | Chemistry |
| Thesis Availability: | Public (worldwide access) |
| Research Advisor(s): |
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| Thesis Committee: |
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| Defense Date: | 1951 |
| Record Number: | CaltechTHESIS:10162017-102130831 |
| Persistent URL: | https://resolver.caltech.edu/CaltechTHESIS:10162017-102130831 |
| DOI: | 10.7907/CMRX-8587 |
| Default Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. |
| ID Code: | 10518 |
| Collection: | CaltechTHESIS |
| Deposited By: | Benjamin Perez |
| Deposited On: | 16 Oct 2017 19:34 |
| Last Modified: | 02 May 2023 16:30 |
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