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The photoreactions of N-methyl-2-pyridone

Citation

Sharp, Louis James (1970) The photoreactions of N-methyl-2-pyridone. Dissertation (Ph.D.), California Institute of Technology. http://resolver.caltech.edu/CaltechETD:etd-02272009-095718

Abstract

In studying the photochemistry of N-methyl-2- pyridone, four products were observed. Besides the previously known dimer and bicyclic monomer, two new dimers were isolated.

The quantum yields of product formation were measured, and it was found that only one intermediate was involved. From sensitization and quenching experiments, the lowest excited singlet state appears to be that intermediate although a highly reactive, ground state isomer cannot be ruled out. Some spectroscopic evidence for this isomer is given.

Item Type:Thesis (Dissertation (Ph.D.))
Degree Grantor:California Institute of Technology
Division:Chemistry and Chemical Engineering
Major Option:Chemistry
Thesis Availability:Public (worldwide access)
Research Advisor(s):
  • Hammond, George Simms
Thesis Committee:
  • Unknown, Unknown
Defense Date:18 August 1969
Record Number:CaltechETD:etd-02272009-095718
Persistent URL:http://resolver.caltech.edu/CaltechETD:etd-02272009-095718
Default Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:794
Collection:CaltechTHESIS
Deposited By: Imported from ETD-db
Deposited On:06 Mar 2009
Last Modified:26 Dec 2012 02:32

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