Silver, Marc Stamm (1959) Intermediates in carbonium ion reactions of methyl-substituted cyclopropylcarbinyl, cyclobutyl and allylcarbinyl derivatives. Dissertation (Ph.D.), California Institute of Technology. http://resolver.caltech.edu/CaltechETD:etd-02172006-092624
The products of the nitrous acidination of 2-methylcyclobutylamine, 3-methylcyclobutylamine, 2-methylcyclopropylcarbinylamine, cyclopropylmethylcarbinylamine, allylmethylcarbinylamine and crotylcarbinylamine have been determined. In addition, studies on the rates of solvolysis of suitable derivatives of the same carbon skeleton have been carried out. The experimental data are reminiscent of those reported for the reactions of unsubstituted cyclobutyl, cyclopropylcarbinyl and allylcarbinyl compounds and are interpreted in terms of cationic intermediates closely related to those proposed for the latter substances. In the present case, the intermediates are most reasonably represented as three non-classical, unsymmetrical, non-equivalent pyramidal ions, "bicyclobutonium" ions.
|Item Type:||Thesis (Dissertation (Ph.D.))|
|Degree Grantor:||California Institute of Technology|
|Division:||Chemistry and Chemical Engineering|
|Thesis Availability:||Public (worldwide access)|
|Defense Date:||1 January 1959|
|Default Usage Policy:||No commercial reproduction, distribution, display or performance rights in this work are provided.|
|Deposited By:||Imported from ETD-db|
|Deposited On:||21 Feb 2006|
|Last Modified:||26 Dec 2012 02:31|
- Final Version
See Usage Policy.
Repository Staff Only: item control page