Shah, Usha (1964) α-carbonium ion stabilization in derivatives of cyclopentadienylmanganese tricarbonyl. Master's thesis, California Institute of Technology. http://resolver.caltech.edu/CaltechTHESIS:05032010-131343121
A study has been made of the solvolyses of some acetoxy and trifluoroacetoxy compounds of cyclopentadienylmanganese tricarbonyl and of benzene. Also, a study of some addition reactions to the double bond of vinyl cyclopentadienylmanganese tricarbonyl has been made. Both studies show that an α-cyclopentadienylmanganese tricarbonyl carbonium ion is less stable than an α-ferrocenylcarbonium ion, but more stable than an α-phenylcarbonium ion.
|Item Type:||Thesis (Master's thesis)|
|Degree Grantor:||California Institute of Technology|
|Division:||Chemistry and Chemical Engineering|
|Thesis Availability:||Public (worldwide access)|
|Defense Date:||1 January 1964|
|Default Usage Policy:||No commercial reproduction, distribution, display or performance rights in this work are provided.|
|Deposited By:||Tony Diaz|
|Deposited On:||17 Jun 2010 15:43|
|Last Modified:||26 Dec 2012 03:25|
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