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Nuclear magnetic resonance spectroscopy cyclopropane derivatives

Citation

Patel, Dinshaw J. (1963) Nuclear magnetic resonance spectroscopy cyclopropane derivatives. Master's thesis, California Institute of Technology. http://resolver.caltech.edu/CaltechTHESIS:04302010-094941787

Abstract

Chemical shifts and coupling constants have been determined from the analysis of proton nuclear magnetic resonance spectra for a series of cyclopropane derivatives . The geminal and vicinal cyclopropyl couplings have opposite signs. Additional ^(13)C-H coupling constants have been obtained for cyclopropanes which support the conclusion that the hybridization in cyclopropanes is close to sp^2. The chemical shifts for several cyclopropanes seem consistent with a ring-current effect.

Item Type:Thesis (Master's thesis)
Subject Keywords:Chemistry
Degree Grantor:California Institute of Technology
Division:Chemistry and Chemical Engineering
Major Option:Chemistry
Thesis Availability:Public (worldwide access)
Research Advisor(s):
  • Roberts, John D.
Thesis Committee:
  • Unknown, Unknown
Defense Date:1 January 1963
Record Number:CaltechTHESIS:04302010-094941787
Persistent URL:http://resolver.caltech.edu/CaltechTHESIS:04302010-094941787
Default Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:5760
Collection:CaltechTHESIS
Deposited By: Tony Diaz
Deposited On:16 Jul 2010 16:24
Last Modified:26 Dec 2012 03:25

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