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Nuclear magnetic resonance spectroscopy cyclopropane derivatives


Patel, Dinshaw J. (1963) Nuclear magnetic resonance spectroscopy cyclopropane derivatives. Master's thesis, California Institute of Technology.


Chemical shifts and coupling constants have been determined from the analysis of proton nuclear magnetic resonance spectra for a series of cyclopropane derivatives . The geminal and vicinal cyclopropyl couplings have opposite signs. Additional ^(13)C-H coupling constants have been obtained for cyclopropanes which support the conclusion that the hybridization in cyclopropanes is close to sp^2. The chemical shifts for several cyclopropanes seem consistent with a ring-current effect.

Item Type:Thesis (Master's thesis)
Subject Keywords:Chemistry
Degree Grantor:California Institute of Technology
Division:Chemistry and Chemical Engineering
Major Option:Chemistry
Thesis Availability:Public (worldwide access)
Research Advisor(s):
  • Roberts, John D.
Thesis Committee:
  • Unknown, Unknown
Defense Date:1 January 1963
Record Number:CaltechTHESIS:04302010-094941787
Persistent URL:
Default Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:5760
Deposited By: Tony Diaz
Deposited On:16 Jul 2010 16:24
Last Modified:26 Dec 2012 03:25

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