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Experiments in nuclear magnetic resonance

Citation

Bromberg, J. Philip (1959) Experiments in nuclear magnetic resonance. Master's thesis, California Institute of Technology. http://resolver.caltech.edu/CaltechTHESIS:11242009-075328528

Abstract

I. Proton and cobalt resonances were observed in single crystals of Co(NH_2CH_2CH_2NH_2)_3Cl_3 ^3H_2_O. The cobalt spectrum consists of a maximum of seven lines whose separation follows a (3cos^2θ – 1) dependence quite closely where θ is the angle between the c-axis of the crystal and H_o. The spectrum is fully explained on the basis of quadrupole interaction. Two sets of doublets were found for the proton resonances; an inner, very narrow set following a dependence similar to the cobalt resonance, and a pair of outer broad peaks which overlap the sharp peaks. The narrowness of the central peaks is attributed to internal rotation of one of the proton bearing groups. II. A summary is given of various high resolution spectra of compounds related to phosphine.

Item Type:Thesis (Master's thesis)
Subject Keywords:Chemistry
Degree Grantor:California Institute of Technology
Division:Chemistry and Chemical Engineering
Major Option:Chemistry
Thesis Availability:Public (worldwide access)
Research Advisor(s):
  • McConnell, Harden M.
Thesis Committee:
  • Unknown, Unknown
Defense Date:1 January 1959
Funders:
Funding AgencyGrant Number
Sloan Foundation fellowship (1958)UNSPECIFIED
Record Number:CaltechTHESIS:11242009-075328528
Persistent URL:http://resolver.caltech.edu/CaltechTHESIS:11242009-075328528
Default Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:5396
Collection:CaltechTHESIS
Deposited By: Tony Diaz
Deposited On:01 Dec 2009 18:32
Last Modified:26 Dec 2012 03:19

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