Brown, Raymond A. (1947) The formal potential of the antimonous-antimonic couple in hydrochloric acid and a method for the determination of tripositive antimony. Master's thesis, California Institute of Technology. http://resolver.caltech.edu/CaltechETD:etd-10052005-162608
1. The antimonous-antimonic half cell formal potential has been found to be -0.746 in 3.5 weight formal HC1, -0.784 in 4.5 weight formal HC1, and -0.818 in 6.0 weight formal HC1 when the total antimony concentration is 3.20x10(-2) weight formal.
2. The dependence of the formal potential upon total antimony concentration and the ratio Sb(+III)/Sb(+V) has been studied.
3. Tripositive antimony has been determined in quantities ranging from 10 to 1,500 micrograms by coulometric titration in hydrochloric acid solutions containing bromide with electrolytically generated bromine using an amperometric end point.
|Item Type:||Thesis (Master's thesis)|
|Degree Grantor:||California Institute of Technology|
|Division:||Chemistry and Chemical Engineering|
|Thesis Availability:||Public (worldwide access)|
|Defense Date:||1 January 1947|
|Default Usage Policy:||No commercial reproduction, distribution, display or performance rights in this work are provided.|
|Deposited By:||Imported from ETD-db|
|Deposited On:||06 Oct 2005|
|Last Modified:||26 Dec 2012 03:04|
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