Citation
Greene, Blake Bennet (2004) Progress toward the total synthesis of salvadione-A and related diterpenoids. Master's thesis, California Institute of Technology. http://resolver.caltech.edu/CaltechETD:etd-06252004-084128
Abstract
Herein, we report our progress toward the total synthesis of salvadione-A, a structurally complex triterpenoid isolated from Salvia bucharica. We document a model system of our tandem Claisen/Cope/Diels-Alder strategy. Additionally, we describe the evolution of our strategy toward the synthesis of three structurally related diterpenoids-coulterone, cyclocoulterone, and komaroviquinone--from a cyclopropanation/Friedel-Crafts route to an anionic homo-Fries/intramolecular Barbier cyclization pathway.
| Item Type: | Thesis (Master's thesis) |
|---|---|
| Degree Grantor: | California Institute of Technology |
| Division: | Chemistry and Chemical Engineering |
| Major Option: | Chemistry |
| Thesis Availability: | Restricted to Caltech community only |
| Research Advisor(s): |
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| Thesis Committee: |
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| Defense Date: | 1 March 2004 |
| Record Number: | CaltechETD:etd-06252004-084128 |
| Persistent URL: | http://resolver.caltech.edu/CaltechETD:etd-06252004-084128 |
| Default Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. |
| ID Code: | 2720 |
| Collection: | CaltechTHESIS |
| Deposited By: | Imported from ETD-db |
| Deposited On: | 28 Jun 2004 |
| Last Modified: | 26 Dec 2012 02:53 |
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