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Progress toward the total synthesis of salvadione-A and related diterpenoids


Greene, Blake Bennet (2004) Progress toward the total synthesis of salvadione-A and related diterpenoids. Master's thesis, California Institute of Technology.


Herein, we report our progress toward the total synthesis of salvadione-A, a structurally complex triterpenoid isolated from Salvia bucharica. We document a model system of our tandem Claisen/Cope/Diels-Alder strategy. Additionally, we describe the evolution of our strategy toward the synthesis of three structurally related diterpenoids-coulterone, cyclocoulterone, and komaroviquinone--from a cyclopropanation/Friedel-Crafts route to an anionic homo-Fries/intramolecular Barbier cyclization pathway.

Item Type:Thesis (Master's thesis)
Degree Grantor:California Institute of Technology
Division:Chemistry and Chemical Engineering
Major Option:Chemistry
Thesis Availability:Restricted to Caltech community only
Research Advisor(s):
  • Stoltz, Brian M.
Thesis Committee:
  • Unknown, Unknown
Defense Date:1 March 2004
Record Number:CaltechETD:etd-06252004-084128
Persistent URL:
Default Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:2720
Deposited By: Imported from ETD-db
Deposited On:28 Jun 2004
Last Modified:26 Dec 2012 02:53

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