Farrar, Grover Louis (1961) Part I: Cis- and trans-1,2-diaminocyclohexanes. Part II: A study of the tertiary amine precursors of pirylene. Dissertation (Ph.D.), California Institute of Technology. http://resolver.caltech.edu/CaltechETD:etd-03282006-131742
PART I: cis- and trans-1,2-Diaminocyclohexanes:
Work initiated in these laboratories by Reims and Buchman on the stereospecific conversion of cis- and trans-cyclohexane-1,2-dicarboxylic acids to the corresponding diamines has been extended. cis- and trans-1,2-Diaminocyclohexanes have been characterized by measurements of densities, refractive indices, acid constants and melting points and by preparations of both side-chain and cyclic derivatives.
PART II: A study of the tertiary amine precursors of pirylene:
The observation of Sargent, Buchman and Farquhar, that the Hofmann degradation of N,N-dimethyl-[alpha]-bromomethylpyrrolidinium bromide does not give a single C7H13N amine, but a mixture of isomeric tertiary amines has been confirmed. The components of the C7H13N amine mixture have been identified as follows:
Components (2), (4) and (5) have been isolated and characterized. Components (1) and (3) were detected by infrared spectroscopy.
A probable course of formation of the C7H13N amine mixture from N,N-dimethyl-[alpha]-bromomethylpyrrolidinium bromide is discussed.
|Item Type:||Thesis (Dissertation (Ph.D.))|
|Degree Grantor:||California Institute of Technology|
|Division:||Chemistry and Chemical Engineering|
|Thesis Availability:||Public (worldwide access)|
|Defense Date:||1 January 1961|
|Default Usage Policy:||No commercial reproduction, distribution, display or performance rights in this work are provided.|
|Deposited By:||Imported from ETD-db|
|Deposited On:||31 Mar 2006|
|Last Modified:||26 Dec 2012 02:36|
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